The third largest solar proton event in the past thirty years took place du
ring July 14-16, 2000, and had a significant impact on the earth's atmosphe
re. These energetic protons produced both HOx (H, OH, HO2) and NOx (N, NO,
NO2) constituents in the mesosphere and upper stratosphere at polar latitud
es (> 60 degrees geomagnetic) of both hemispheres. The temporal evolution o
f increases in NO and NO2 during the event at northern polar latitudes were
measured by the UARS HALOE instrument. Increases in mesospheric NO, of ove
r 50 ppbv were found in the HALOE measurements. Measurements from the UARS
HALOE and NOAA 14 SBUV/2 instruments indicate short-term (similar to day) m
iddle mesospheric ozone decreases of over 70% caused by short-lived HOx dur
ing the event with a longer-term (several days) upper stratospheric ozone d
epletion of up to 9% caused by longer-lived NOx. We believe this is the fir
st time that the three constituents NO, NO2, and ozone were all measured si
multaneously during a proton event. The observations constitute a dramatic
confirmation of the impact of a large particle event in the control of ozon
e in the polar middle atmosphere and offer the opportunity to test theories
of constituent changes driven by particle precipitation.