An increase in the off-nadir viewing angle for an airborne visible/near-inf
rared through short-wave infrared (VNIR/SWIR) imaging spectrometer leads to
a decrease in upward atmospheric transmittance and an increase in line-of-
sight scattered path radiance. These effects combine to reduce the spectral
contrast between different materials in the sensed, signal. We analyze the
impact of viewing angle on material discriminability for 237 materials ove
r a wide range of conditions. Material discriminability is quantified using
a statistical algorithm that employs a subspace model to represent the set
of spectra for a material as conditions vary. We show that reliable materi
al discrimination is possible over a range of conditions even for large off
-nadir viewing angles. We illustrate the performance of material identifica
tion over different viewing angles using simulated forest and desert hypers
pectral digital imagery collection experiment (HYDICE) images.