At-sensor thermal infrared (TIR) radiation varies depending on the temperat
ure and emissivity of surface materials and the modifying impact of atmosph
eric absorption and emission. TIR imaging spectrometry often involves extra
cting temperature, emissivity, and/or surface composition, which are useful
in diverse studies ranging from climatology to land use analyses. A two-st
age application of temperature emissivity separation (TES) using spectral m
ixture analysis (SMA) or TESSMA, was employed to characterize isothermal mi
xtures on a subpixel basis. This two-stage approach first uses the relation
ship between a virtual cold endmember fraction and surface temperature to e
xtract initial image temperature estimates. Second, an isothermal SMA appli
cation searches the region within the maximum temperature error range of th
e initial estimate, selecting the best subpixel spectral mixture fit. Work
presented includes characterizations of synthetically generated temperature
and constituent mixture gradient test images, and a discussion of errors a
ssociated with selecting temperature search ranges 25% and 75% smaller than
the initial temperature calculation error range. Results using this two-st
age approach indicate improved overall temperature estimates, constituent e
stimates, and constituent fraction estimates using simulated TIR data.