Y. Terada et al., Site preference determination in intermetallic compounds by thermal conductivity measurement, J MATER RES, 16(8), 2001, pp. 2314-2320
A method for the determination of site preference of substitutional element
s in intermetallic compounds is proposed. It is demonstrated in Ni3Al-X all
oys that the ridge direction in thermal conductivity contours in the ternar
y gamma' phase agrees with that of the solubility lobe of the gamma' phase
in ternary phase diagrams. The ridce direction is a reliable indication of
site preference of substitutional elements in intermetallic compounds. The
present method is conveniently applied to a normal polycrystalline specimen
with small size, and therefore, a versatile class of brittle compounds can
be studied.