A novel supramolecular compound with three-dimensional hydrogen-bonded network [Hbet](3)[Fe(CN)(6)]center dot 4H(2)O: synthesis, characterization andcrystal structure

Authors
Yan, B Wang, HD Chen, ZD
Citation
B. Yan et al., A novel supramolecular compound with three-dimensional hydrogen-bonded network [Hbet](3)[Fe(CN)(6)]center dot 4H(2)O: synthesis, characterization andcrystal structure, J MOL STRUC, 569(1-3), 2001, pp. 65-70
Citations number
8
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF MOLECULAR STRUCTURE
ISSN journal
00222860 → ACNP
Volume
569
Issue
1-3
Year of publication
2001
Pages
65 - 70
Database
ISI
SICI code
0022-2860(20010719)569:1-3<65:ANSCWT>2.0.ZU;2-U
Abstract
A hydrogen-bonded supramolecular compound, [Hbet](3)[Fe(CN)(6)]. 4H(2)O, ha s been synthesized from betaine ((CH3)(3)N+CH3CO2-) (bet) and K-3[Fe(CN)(6) ] and structurally characterized. The crystal structure consists of neutral two-dimensional sheets assembled via hydrogen bonding between the protonat ed betaine (Hbet(+)) and the hexacyanoferrate(RI) ion, while the hydrogen b onding involving water molecules interlinks the sheets to form a unique thr ee-dimensional supramolecular architecture. (C) 2001 Elsevier Science B.V. All rights reserved.