Citation
Dr. Ahn et al., Induction of diastereoselectivity in Fe(II) tris(amino acid-bipyridine) complexes, J ORG CHEM, 66(15), 2001, pp. 5008-5011
Citations number
21
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANIC CHEMISTRY
ISSN journal
00223263
→ ACNP
Volume
66
Issue
15
Year of publication
2001
Pages
5008 - 5011
Database
ISI
SICI code
0022-3263(20010727)66:15<5008:IODIFT>2.0.ZU;2-M
Abstract
A group of iron(II) tris-bipyridine complexes bearing L-amino acids (L-Lys,
L-Phe, L-Ser, L-Val) was prepared to investigate the predetermination of c
hirality of metal complexes by the chiral amino acid subunits. Noncovalent
interactions and solvent polarity seemed to be important factors in inducin
g diastereoselectivity of the metal complexes. These phenomena were explain
ed by H-1 NMR and CD spectroscopic studies and molecular mechanics calculat
ions.