The initial stages Of O-2 oxidation of H-passivated flat and vicinal Si(1 1
1) surfaces are investigated by monitoring the Si-H stretch vibrations wit
h infrared absorption spectroscopy. We find that the incorporation of oxyge
n into silicon is activated (1.66 +/-0.10 CV on flat surfaces), involving a
multistep process. Oxygen molecules are incorporated into Si-Si bonds with
out removing surface hydrogen and this process is facilitated at steps. (C)
2001 American Vacuum Society.