Dn. Futaba et al., Scanning tunneling microscopy study of the molecular arrangement of meta- and para-xylene on Pd(111), J VAC SCI A, 19(4), 2001, pp. 1993-1995
We have performed an experimental study of meta- and para-xylene isomers, C
6H4(CH3)(2), adsorbed on Pd(111). Using scanning tunneling microscopy we im
aged the characteristic surface structures and investigated the molecular o
rdering for meta- and para-xylene. A triangular shape characterized the met
a-xylene, and the para-xylene showed a distinctive diamond shape. Both isom
ers showed some propensity to order and a correlation between azimuthal ori
entation and the close-packed directions of the metal. (C) 2001 American Va
cuum Society.