Tube models for rubber-elastic systems

Citation
B. Mergell et R. Everaers, Tube models for rubber-elastic systems, MACROMOLEC, 34(16), 2001, pp. 5675-5686
Citations number
51
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
MACROMOLECULES
ISSN journal
00249297 → ACNP
Volume
34
Issue
16
Year of publication
2001
Pages
5675 - 5686
Database
ISI
SICI code
0024-9297(20010731)34:16<5675:TMFRS>2.0.ZU;2-K
Abstract
In the first part of the paper, we show that the constraining potentials in troduced to mimic entanglement effects in Edwards' tube model and Flory's c onstrained junction model are diagonal in the generalized Rouse modes of th e corresponding phantom network. As a consequence, both models can formally be solved exactly for arbitrary connectivity using the recently introduced constrained mode model. In the second part, we solve a double tube model f or the confinement of long paths in polymer networks which is partially due to cross-linking and partially due to entanglements. Our model describes a nontrivial crossover between the Warner-Edwards and the Heinrich-Straube t ube models. We present results for the macroscopic elastic properties as we ll as for the microscopic deformations including structure factors.