We fabricated two kinds of phosphorescent polymer light emitting devices us
ing two different phosphorescent emitters doped in a host polymer poly (vin
ylcarbazole) (PVK). Octaethylporphine platinum(II) (PtOEP) and tris(2-pheny
lpyridine) iridium [Ir(ppy)(3)] were used as the guest emitters in the devi
ces, respectively. The doping concentrations of the PtOEP and [Ir(ppy)(3)]
were 6 and 8%, respectively. The emission spectra of the devices exhibited
no emission from PVK, indicating that the energy transfer from PVK to guest
molecules is efficient. The maximum quantum efficiency was 0.6 and 1.9% at
low current for PtOEP and [lr(ppy)(3)] doped devices, respectively. The ef
ficiency decreased as the current increased for both devices. However, the
decreasing rate was slower for the [Ir(ppy)(3)] doped device, which may res
ult from the shorter triplet exciton life time of [Ir(ppy)(3)] than that of
PtOEP. The devices showed maximum brightness of 240 and 2500 cd m(-2) for
the PtOEP and [Ir(ppy)(3)] doped devices, respectively. (C) 2001 Elsevier S
cience B.V. All rights reserved.