The Palim granite, hosted by the metasedimentary country rocks in the Basta
r tin province, is a heterogeneous pluton that comprises hornblende granite
, biotite granite and two-mica granite. Spherical inhomogeneous surmicaceou
s enclaves occur within the granites with coarse grained cores of muscovite
mantled by finer muscovite-quartz-biotite ( sillimanite) rims. Geochemical
features imply that the granites are highly evolved and geochemically dist
inct. Petrographic and geochemical considerations point towards a transitio
n from metaluminous I-type hornblende-bearing granite in the south to peral
uminous volatile-enriched S-type like lithologies (biotite and two-mica gra
nites) towards north. Modeling of highly incompatible elements such as Nb a
nd Cs, implies 31 to 33% assimilated fractional crystallization of a melt w
ith an initial composition close to that of the hornblende granite to form
the two-mica granite. Hornblende geobarometry, plagioclase-hornblende therm
ometry (in hornblende granite) and phengite barometry (in two-mica granite)
, yield P-T estimates of 5-7kb/725 degrees -760 degreesC, and 6 kb/700 degr
eesC, respectively. The study further implies that a genetic link exists be
tween granite magmatism and the formation of tin pegmatites in the region.
The preponderance of peripheral pegmatites to the north-east of the Palim g
ranite is regarded a result of outward crystal-melt fractionation and tecto
nic tilting of the pluton.