The structure of a Cd68Mg12Dy20 crystalline phase denoted as the phi -phase
, which has a composition close to that of the Cd(66)Mg(21)Dv(13) icosahedr
al quasicrystalline phase. has been investigated by electron diffraction an
d scanning transmission electron microscopy (STEM). The phase has a fcc lat
tice with a = 21.6 Angstrom. High-angle annular dark-field STEM with Z cont
rast confirms that the phase has the Cd45Sm11-type structure. The atomic cl
uster in the structure is shown to be characterized by a Friauf polyhedron
with tetrahedral symmetry.