Guanidine in the synthesis of perfluoroalkylpyrimidines and perfluoroalkyl-s-triazines

Authors
Furin, GG Gatilov, YV Bagryanskaya, IY Zhuzhgov, EL
Citation
Gg. Furin et al., Guanidine in the synthesis of perfluoroalkylpyrimidines and perfluoroalkyl-s-triazines, RUSS CHEM B, 50(3), 2001, pp. 476-479
Citations number
11
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 → ACNP
Volume
50
Issue
3
Year of publication
2001
Pages
476 - 479
Database
ISI
SICI code
1066-5285(200103)50:3<476:GITSOP>2.0.ZU;2-J
Abstract
Perfluoro-2-methylpent-2-ene and perfluoro-5-azanon-4-ene react with guanid ine hydrochloride in the presence of triethylamine to give 2-amino-6-fluoro -4-pentafluoroethyl-5-trifluoromethylpyrimidine and 2-amino-4,6-bis(heptafl uoropropyl)-1,3,5-triazine, respectively. The structure of the former produ ct was confirmed by X-ray diffraction analysis.