Oxidative dehydrogenation of N-methyl-o-phenylenediamine coordinated to the Pd-II and Pt-II atoms

Authors
Fomina, IG Talismanov, SS Sidorov, AA Ustynyuk, YA Nefedov, SE Eremenko, IL Moiseev, II
Citation
Ig. Fomina et al., Oxidative dehydrogenation of N-methyl-o-phenylenediamine coordinated to the Pd-II and Pt-II atoms, RUSS CHEM B, 50(3), 2001, pp. 515-519
Citations number
7
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 → ACNP
Volume
50
Issue
3
Year of publication
2001
Pages
515 - 519
Database
ISI
SICI code
1066-5285(200103)50:3<515:ODONCT>2.0.ZU;2-R
Abstract
The reactions of N-methyl-ortho-phenylenediamine (1) with K2MCl4 (M = Pd or PQ were investigated. At the first stage, the tetraamine dicationic comple xes [(C6H4(NH2)(NMeH))(2)M]Cl-2 were formed. Oxidation of these compounds W ith atmospheric oxygen in an alkaline medium afforded the neutral semiquino nediimine complexes [C6H4(NH)(N-Me)](2)M. The structures of the {[(C6H4)(NH 2)(NHMe)](2)Pd}Cl-2 and [C6H4(NH)(NPh)](2)Pt complexes were established by X-ray diffraction analysis.