Derivatives of phosphorous acid as a new class of ligands for Pd-catalyzedallylation

Citation
Sk. Moiseev et al., Derivatives of phosphorous acid as a new class of ligands for Pd-catalyzedallylation, RUSS CHEM B, 50(3), 2001, pp. 554-556
Citations number
15
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 → ACNP
Volume
50
Issue
3
Year of publication
2001
Pages
554 - 556
Database
ISI
SICI code
1066-5285(200103)50:3<554:DOPAAA>2.0.ZU;2-H
Abstract
Amido- and aminophosphites and hydrospirophosphoranes can be used as ligand s in the Pd-catalyzed allylation of ethyl malonate with ethyl (3-phenylprop -2-enyl) carbonate. Bidentate ligands (RO)(2)P-O(CH2)(n)-NR ' (2) (n = 2 an d 3) were found to be the most effective ligands.