Influence of supporting electrolyte cation on extraction of zinc with quinoline N-oxide from alkali metal bromide solutions

Authors
Tunina, SG Andreev, VP Ershova, NY Nizhnik, YP
Citation
Sg. Tunina et al., Influence of supporting electrolyte cation on extraction of zinc with quinoline N-oxide from alkali metal bromide solutions, RUSS J G CH, 70(12), 2000, pp. 1867-1871
Citations number
16
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
ISSN journal
10703632 → ACNP
Volume
70
Issue
12
Year of publication
2000
Pages
1867 - 1871
Database
ISI
SICI code
1070-3632(200012)70:12<1867:IOSECO>2.0.ZU;2-8
Abstract
Extraction of zinc at 298 K with quinoline N-oxide from solutions of alkali metal (Na+, K+, Rb+) bromides with the constant ionic strength (1, 1.5, 2, 3) supported by alkali metal nitrate was studied. The zinc extraction cons tants and the stability constants of its bromide complexes at the given ion ic strengths were calculated. A linear correlation was revealed between the zinc extraction constant and the enthalpy of hydration of the supporting e lectrolyte cation.