Physico-chemical and engineering principles of boron isotopes separation by using BF3-anisole center dot BF3 system

Authors
Citation
Sg. Katalnikov, Physico-chemical and engineering principles of boron isotopes separation by using BF3-anisole center dot BF3 system, SEP SCI TEC, 36(8-9), 2001, pp. 1737-1768
Citations number
43
Categorie Soggetti
Chemistry
Journal title
SEPARATION SCIENCE AND TECHNOLOGY
ISSN journal
01496395 → ACNP
Volume
36
Issue
8-9
Year of publication
2001
Pages
1737 - 1768
Database
ISI
SICI code
0149-6395(2001)36:8-9<1737:PAEPOB>2.0.ZU;2-U
Abstract
This review is devoted to consideration of physico-chemical and engineering data required for realization of boron isotopes separation by ti a method of chemical isotope exchange between BF3 and the complex anisole.BF3. The p roperties of the initial substances and anisole.BF3 complex required for ca lculation of the separation process are considered. The data on phase equil ibrium in the system, isotope equilibrium, kinetics of interphase isotope e xchange, and implementation of phases conversion are presented. This articl e considers comprehensively the reasons for anisole decomposition and the m easures for its prevention. The problem of hydrodynamics and choice of pack ing are investigated. The conditions of initial substances preparation are treated. Perspective trends of separation process improvement are discussed .