This paper reports the development of a method for real-time automated quan
titative analysis of mineral ores using a commercial laser-induced breakdow
n spectroscopy instrument, TRACER (TM) 2100, fitted with a recently develop
ed computer controlled auto-sampler. The auto-sampler permits the execution
of methods for performing calibrations and analysis of multiple elements o
n multiple samples. Furthermore, the analysis is averaged over multiple loc
ations on each sample, thus compensating for heterogeneous morphology. The
results for phosphate ore are reported here, but similar methods are being
developed for a range of ores and minerals. Methods were developed to autom
atically perform metallic element calibrations for supplied phosphate ore s
amples containing known concentrations of the following minerals: P2O5, CaO
, MgO, SiO2 and Al2O3. A spectral line for each desired element was selecte
d with respect to the best combination of peak intensity and minimum interf
erences from other lines. This is a key step, because of the observed matri
x dependence of the technique. The optimum combination of the time interval
between the laser firing (plasma formation), signal detection, and the dur
ation of the optical detection was then determined for each element, to opt
imize spectral line intensity and resolution. The instrument was capable of
analyzing the required elements in the phosphate ore samples supplied with
2-4% relative standard deviations for most elements. Calibrations were ach
ieved for P, Ca, Mg, Al and Si with linear regression coefficients of 0.985
, 0.980, 0.993, 0.987 and 0.985, respectively. Preparation and analysis tim
e for each sample was less than 5 min. (C) 2001 Elsevier Science B.V. All r
ights reserved.