Mavr. Da Silva et al., Standard enthalpies of formation of 2,6-di-tert-butyl-4-methylphenol and 3,5-di-tert-butylphenol and their phenoxy radicals, STRUCT CHEM, 12(2), 2001, pp. 171-181
The standard (p(o) = 0.1 MPa) enthalpies of formation of 2,6-di-tert-butyl-
4-methylphenol and 3,5-di-tert-butylphenol in the gaseous phase, -315.5 +/-
4.4 kJ mol(-1) and -312.7 +/- 4.6 kJ mol(-1), respectively, were derived f
rom the standard enthalpies of combustion, in oxygen, at 298.15 K, measured
by static bomb combustion calorimetry, and from the standard enthalpies of
sublimation, at 298.15 K, measured by Calvet microcalorimetry. The O-H bon
d dissociation enthalpies in those compounds were determined in benzene by
photoacoustic calorimetry, leading to the standard enthalpies of formation
of the gaseous phenoxy radicals: -189 +/- 8 kJ mol(-1) and -154 +/- 6 kJ mo
l(-1), respectively. These results were used to calculate enthalpies of sub
stituent redistribution reactions, which are proposed as a method to estima
te new data for substituted phenols.