Facile synthesis of 1,3-dichlorotetra-organodisilazanes

Authors
Xu, CH Zheng, ZM Li, YM Zhang, ZJ Xie, ZM
Citation
Ch. Xu et al., Facile synthesis of 1,3-dichlorotetra-organodisilazanes, SYN COMMUN, 31(15), 2001, pp. 2271-2275
Citations number
11
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNTHETIC COMMUNICATIONS
ISSN journal
00397911 → ACNP
Volume
31
Issue
15
Year of publication
2001
Pages
2271 - 2275
Database
ISI
SICI code
0039-7911(2001)31:15<2271:FSO1>2.0.ZU;2-Y
Abstract
A new 1,3-dichlorodisflazane, 1,3-dichloro-1,3-dimethyl-1,3-divinyldisilaza ne (DMDV), was prepared from the trans-silylation reaction of hexamethyldis ilazane (MMN) and methyl-vinyldichlorosilane. The reactions between MMN and other dichlorosilanes, R2SiCl2 (R =Me, Ph) in the absence of catalyst were also investigated, and the expected, 1,3-dichlorosilazanes, (ClSiMe2)(2)NH and (ClSiPh2)(2)NH were obtained, respectively.