A mild and feasible deprotection of alcohol tetrahydropyranyl or methoxymethyl ethers catalyzed by Sc(OTf)(3)

Authors
Oriyama, T Watahiki, T Kobayashi, Y Hirano, H Suzuki, T
Citation
T. Oriyama et al., A mild and feasible deprotection of alcohol tetrahydropyranyl or methoxymethyl ethers catalyzed by Sc(OTf)(3), SYN COMMUN, 31(15), 2001, pp. 2305-2311
Citations number
36
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNTHETIC COMMUNICATIONS
ISSN journal
00397911 → ACNP
Volume
31
Issue
15
Year of publication
2001
Pages
2305 - 2311
Database
ISI
SICI code
0039-7911(2001)31:15<2305:AMAFDO>2.0.ZU;2-Y
Abstract
Tetrahydropyranyl or methoxymethyl ethers can be easily deprotected by trea tment of-a catalytic amount of scandium trifluoromethanesulfonate along wit h methanol or 1,3-propanediol, respectively, to afford the corresponding pa rent alcohols in high to excellent yields.