Stereoselective electrochemical transformation of 4-substituted cyclohexanones into cis-5-substituted-2,2-dimethoxycyclohexanols

Authors
Elinson, MN Feducovich, SK Dmitriev, DE Dorofeev, AS Vereshchagin, AN Nikishin, GI
Citation
Mn. Elinson et al., Stereoselective electrochemical transformation of 4-substituted cyclohexanones into cis-5-substituted-2,2-dimethoxycyclohexanols, TETRAHEDR L, 42(32), 2001, pp. 5557-5559
Citations number
30
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
42
Issue
32
Year of publication
2001
Pages
5557 - 5559
Database
ISI
SICI code
0040-4039(20010806)42:32<5557:SETO4C>2.0.ZU;2-2
Abstract
Electrolysis of 4-substituted cyclohexanones in methanol in the presence of sodium halides in an undivided cell results in the stereoselective formati on of cis - 5-substituted-2,2-dimethoxycyclohexanols in 70-80% yield. (C) 2 001 Elsevier Science Ltd. All rights reserved.