Polyurethane foam medium was manufactured and analyzed to determine its sui
tability as a solid support medium for use in gas-phase biofilters. Physica
l and chemical studies were conducted to determine the medium's characteris
tics. The medium's ability to support an active biofilm capable of degradin
g volatile organic compounds was assessed using a laboratory scale biofilte
r fed a model waste stream containing toluene for more than 250 days with e
mpty bed residence times (EBRTs) ranging from two to four minutes. Results
are presented that show how a polyurethane foam medium with high porosity,
suitable pore size, low density, and an ability to sorb water was able to r
emove over 99% of the influent toluene when fed at a concentration of 200 p
pm(v). An operating strategy is described which effectively prevented two p
roblems common to conventionally operated biofilter systems: nutrient limit
ations and biosolid accumulation.