Investigations on benz[1,2]oxaphosphinane derivatives

Authors
Malecka, M Budzisz, B
Citation
M. Malecka et B. Budzisz, Investigations on benz[1,2]oxaphosphinane derivatives, ACT CRYST C, 57, 2001, pp. 929-931
Citations number
17
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
57
Year of publication
2001
Part
8
Pages
929 - 931
Database
ISI
SICI code
0108-2701(200108)57:<929:IOBD>2.0.ZU;2-A
Abstract
The structures of two compounds, 3-[1-(2-hydroxyethyl-amino)ethylidene]-2-m ethoxy-3,4-dihydro-1,2 lambda (5)-benzoxaphosphinane-2,4-dione, C13H16NO5P, and 3-[1-(2-hydroxyethylamino)ethylidene]-2-methoxy-6-methyl-3,4-dihydro- 1,2 lambda (5) -benzoxaphosphinane-2,4-dione, C14H18NO5P, have been studied and compared. The oxophosphinane rings have a half-chair conformation and extra six- and five-membered rings are formed by intramolecular N-H . . .O hydrogen bonds. An intermolecular O-H . . .O hydrogen bond is also observed .