N,N '-Bis[tris(hydroxymethyl)methyl]ethanediamide: six O-H center dot center dot center dot O hydrogen bonds generate only a two-dimensional structure

Citation
Jn. Ross et al., N,N '-Bis[tris(hydroxymethyl)methyl]ethanediamide: six O-H center dot center dot center dot O hydrogen bonds generate only a two-dimensional structure, ACT CRYST C, 57, 2001, pp. 949-951
Citations number
24
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
57
Year of publication
2001
Part
8
Pages
949 - 951
Database
ISI
SICI code
0108-2701(200108)57:<949:N'SOCD>2.0.ZU;2-7
Abstract
Molecules of the title compound, C10H20N2O8, adopt a conformation which is almost centrosymmetric. The molecules are disordered over two sets of sites with an occupancy ratio of 0.94:0.06. In the major form, there are two int ramolecular OD H . . .O hydrogen bonds [O . . .O 2.756 (4) and 2.765 (4) An gstrom; O- H . . .O 144 and 146 degrees], in which the two amidic O atoms a ct as acceptors. In addition, there are four intermolecular OD H . . .O hyd rogen bonds [O . . .O 2.650 (3)-2.666 (3) Angstrom; O- H . . .O 158-171 deg rees]; these link each molecule to six others in a continuous sheet structu re which contains five distinct ring motifs, two of the S(7) type, two of t he R-3(3) (10) type and one of the R-2(2) (22) type.