A core collected in the Piallassa Baiona lagoon, a salt-marsh area already
studied for Hg contamination related to nearby industrial sites, was analys
ed for organic micropollutants. Surface sediments show high concentrations
of total PCBs (1148 ng g(-1)), PCDD/Fs (64 ng g(-1)) and PAHs (4801 ng g(-1
)). According to a sedimentation rate of 0.4 cm y(-1), the high increases i
n total PAH, PCB and PCDD/F concentrations began in the 1960's and peaked i
n the 1970s, in parallel with the highest Hg concentrations. Instead, the r
ecent contamination, which primarily involves PCBs and PCDD/Fs, has been ob
served to be unrelated to Hg concentrations. Organic micropollutant concent
rations in the sample core were compared with the sediment quality criteria
provided by international guidelines, and revealed high toxic potential. T
his heavy contamination was also confirmed by comparison with similar envir
onments, particularly the Lagoon of Venice. Further investigations are need
ed to understand better the sources of the recent contamination and to expl
ain the different transfer pathways involved during sedimentation of the "o
ld" material, dumped 20-30 years ago.