BISMUTH(III) DIMETHYLDITHIOARSINATE, BI(S2ASME2)(3) - A NEW DIMER FORMED THROUGH BI...S SECONDARY BONDING

Authors
CEAOLIVARES R EBERT KH SILAGHIDUMITRESCU L HAIDUC I
Citation
R. Ceaolivares et al., BISMUTH(III) DIMETHYLDITHIOARSINATE, BI(S2ASME2)(3) - A NEW DIMER FORMED THROUGH BI...S SECONDARY BONDING, Heteroatom chemistry, 8(4), 1997, pp. 317-321
Citations number
22
Categorie Soggetti
Chemistry
Journal title
Heteroatom chemistry → ACNP
ISSN journal
10427163
Volume
8
Issue
4
Year of publication
1997
Pages
317 - 321
Database
ISI
SICI code
1042-7163(1997)8:4<317:BDB-AN>2.0.ZU;2-2
Abstract
The crystal and molecular structures of bismuth(III) dimethyldithioars inate, Bi(S2AsMe2)(2), were investigated by X-ray diffraction. The com pound is a centrosymmetric dimer in which pentagonal-bipyramidal monom eric units are associated through secondary Bi-S interactions. The str ucture is compared with that of the analogous dithiophosphinate, Bi(S2 PMe2)(3). (C) 1997 John Wiley & Sons, Inc.