Isotope effects on the absorption spectrum of Li in solid hydrogens under high pressures

Citation
Ym. Ma et al., Isotope effects on the absorption spectrum of Li in solid hydrogens under high pressures, CHEM P LETT, 343(5-6), 2001, pp. 604-612
Citations number
27
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
CHEMICAL PHYSICS LETTERS
ISSN journal
00092614 → ACNP
Volume
343
Issue
5-6
Year of publication
2001
Pages
604 - 612
Database
ISI
SICI code
0009-2614(20010810)343:5-6<604:IEOTAS>2.0.ZU;2-2
Abstract
The isotope effects on the absorption spectrum of Li in solid hydrogens at T = 5 K and different pressures are extensively studied. At a lower pressur e, the difference in Li atomic absorption spectra between the Li/D-2 and th e Li/H-2 systems is significant, while becomes less remarkable with the inc rease in pressure. The zero-point motion from H-2 molecules influences the Li absorption spectrum in both a direct and an indirect way. Although the d irect and indirect effects on the absorption spectrum from the quantum moti on cancel partly, eventually the indirect effect dominates the variations o f the Li absorption spectrum. (C) 2001 Elsevier Science B.V. All rights res erved.