Determination of polybrominated diphenyl ethers and PBDD/Fs during the recycling of high impact polystyrene containing decabromodiphenyl ether and antimony oxide
S. Hamm et al., Determination of polybrominated diphenyl ethers and PBDD/Fs during the recycling of high impact polystyrene containing decabromodiphenyl ether and antimony oxide, CHEMOSPHERE, 44(6), 2001, pp. 1353-1360
A high impact polystyrene (HIPS) plastic, flame retarded with decabromodiph
enyl ether (DecaBDE) and antimony trioxide (Sb2O3) has been repeatedly proc
essed and the amount of debromination of the flame retardant and possible f
ormation of PBDD/F was monitored. No indications of debromination were foun
d. The reprocessed (recycled) plastic was found to comply with the German C
hemicals Banning Ordinance. The concentrations of relevant PBDD/F congeners
were at least one order of magnitude below the regulated limit values for
PBDD/F (1 ppb for the sum of four congeners, 5 ppb for the sum of all eight
regulated congeners). (C) 2001 Elsevier Science Ltd. All rights reserved.