The addition of biodiesel together with nitrate and phosphate to soil conta
ining coal tar, in laboratory and field experiments, resulted in degradatio
n of coal tar polycyclic aromatic hydrocarbons (PAH) that was not apparent
when the nutrients alone were added. The addition of motor diesel fuel inst
ead of biodiesel was also tested. Over the 55 days of the field and laborat
ory experiments, the biodiesel resulted in an increased degradation of naph
thalene in the coal tar by 52% and 85%, respectively, and motor diesel resu
lted in increased depletions of 85% and 96%, respectively. Other PAH contai
ning up to four rings were depleted to lesser extents. The increases in PAH
biodegradation by the diesel treatments were ascribed to tar solubilisatio
n and dispersion thereby increasing the PAH bioavailability. The ready biod
egradability and low phytotoxicity of biodiesel suggest that it may be suit
able as a novel treatment for the bioremediation of coal tar contaminated s
oils. (C) 2001 Elsevier Science Ltd. All rights reserved.