A field-deployable instrument has been developed to detect low-level 2,4-di
nitrotoluene (2,4-DNT) vapors. The system is based on previously developed
artificial nose technology and employs an array of sensory materials attach
ed to the distal tips of an optical fiber bundle. Both semiselective and no
nspecific, cross-reactive sensors were employed. Each sensor within the arr
ay responds differentially to vapor exposure so the array's fluorescence re
sponse patterns are unique for each analyte. The instrument is computationa
lly "trained" to discriminate target response patterns from nontarget and b
ackground environments. This detection system has been applied to detect 2,
4-DNT, an analyte commonly detected on the soil surface above buried 2,4,6-
trinitrotoluene (TNT) land mines, in spiked soil and aqueous and ground sam
ples. The system has been characterized and demonstrated the ability to det
ect 120 ppb 2,4-DNT vapor in blind (unknown) humidified samples during a su
pervised field test.