The method of molecular dynamics has been used to study osmosis, reverse os
mosis and electro-osmosis in ethanolic electrolyte solutions. Our results h
ave shown the significant role solvation forces play in reverse osmosis bas
ed separations in a wide range of polar solvents. For instance in NaBr solu
tions, Na+ ions, despite their rather small molecular size, were prevented
from permeating the semi-permeable membrane while ethanol molecules could r
eadily permeate the membrane. This is because of the solvation of the Na+ i
ons by the polar solvent and the rather high energy of desolvation (estimat
ed at about 400 kJ/mol, compared to the hydrogen bond energy of ethanol of
about 20 kJ/mol) makes the solvated ion rather stable. This in effect incre
ases the apparent size of the Na+ ions considerably. In fact, it appears th
at such solvation. and possibly adsorption effects do not even permit the N
a+ ions to get close to the membrane walls, In the past it was thought that
ions are prevented from crossing the membrane due to surface interactions
between the ions and the membrane surface, which were not clearly defined o
r understood. In our studies there were only Lennard-Jones interactions bet
ween the ions and the membrane. We have also found that the rate of osmosis
and reverse osmosis seems to be significantly affected by the selective ad
sorption of the various solution components on the membrane. (C) 2001 Elsev
ier Science B.V. All rights reserved.