The first simple, donor-free salt of the Sb(OTeF5)(6)(-) anion: Synthesis,structure, characterization, and thermochemistry of Cs[Sb(OTeF5)(6)]

Authors
Cameron, TS Krossing, I Passmore, J
Citation
Ts. Cameron et al., The first simple, donor-free salt of the Sb(OTeF5)(6)(-) anion: Synthesis,structure, characterization, and thermochemistry of Cs[Sb(OTeF5)(6)], INORG CHEM, 40(17), 2001, pp. 4488
Citations number
14
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
40
Issue
17
Year of publication
2001
Database
ISI
SICI code
0020-1669(20010813)40:17<4488:TFSDSO>2.0.ZU;2-X
Abstract
Large and nonbasic anions are needed to stabilize novel and highly electrop hilic/oxidizing cations. The Sb(OTeF5)(6)(-)-anion is suitable for this pur pose and can now be introduced as a counterion by metathesis of the here re ported Cs salt with MF6- salts (M = As, Sb) since CsMF6 is insoluble in man y solvents. [GRAPHICS]