Syntheses and structures of bis(azido)- and bis(tert-butoxy)cyclodistibazanes

Authors
Haagenson, DC Stahl, L Staples, RJ
Citation
Dc. Haagenson et al., Syntheses and structures of bis(azido)- and bis(tert-butoxy)cyclodistibazanes, INORG CHEM, 40(17), 2001, pp. 4491
Citations number
45
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
40
Issue
17
Year of publication
2001
Database
ISI
SICI code
0020-1669(20010813)40:17<4491:SASOBA>2.0.ZU;2-5
Abstract
Treatment of the dichlorocyclodistibazane [ClSb(mu -N-t-Bu)(2)SbCl] with al kali-metal azides or tert-butoxides afforded trans-[N3Sb(mu -(NBu)-Bu-t)(2) SbN3] and trans-[Bu-l- OSb(mu -(NBu)-Bu-t)(2)(SbOBu)-Bu-t], respectively. T hese data and other evidence suggest that [ClSb(mu -(NBu)-Bu-t)(2)SbCl], co ntrary to previous assumptions, is a trans isomer also. [GRAPHICS]