Thin films of iron nitrides were deposited by pulsed laser deposition at di
fferent nitrogen pressures. Depositions were done both in the presence as w
ell as absence of glow-discharge around the substrate. Films deposited with
out glow-discharge were essentially ferromagnetic in nature and exhibited a
structural evolution from b.c.c.-->b.c.t.-->f.c.c.-->h.c.p.--> orthorhombi
c phases as the nitrogen pressure during the deposition increased. As a res
ult of glow-discharge during the deposition process, increased nitridation
is obtained and formation of new-cubic-type Fe-N phases occur. (C) 2001 Els
evier Science BV All rights reserved.