Electrochemical sensing of F- and Cl- with a boronic ester-functionalized polypyrrole

Citation
M. Nicolas et al., Electrochemical sensing of F- and Cl- with a boronic ester-functionalized polypyrrole, J ELEC CHEM, 509(1), 2001, pp. 73-79
Citations number
37
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
ISSN journal
15726657 → ACNP
Volume
509
Issue
1
Year of publication
2001
Pages
73 - 79
Database
ISI
SICI code
Abstract
The anodic electropolymerization of pyrrole 3 substituted by a pinacolboran e moiety 1 yielded anion-sensitive conjugated polymer films. The effect of different halides (F-, Cl- and Br-) on the voltammetric response of poly(1) was examined in organic and hydro-organic media. Larger effects were obser ved in CH2Cl2, because of a weaker solvation of anions. In this solvent the system corresponding to the doping/undoping of poly(1) was shifted 450 and 175 mV towards less oxidizing potentials in the presence of F- and Cl-, re spectively. In contrast, the polymer response was unchanged upon the additi on of Br. These results were consistent with a greater affinity of the immo bilized boronic ester groups for F-, which could be explained by the hardne ss of the Lewis base. (C) 2001 Elsevier Science B.V. All rights reserved.