Water represents 80-85% of the volume of mineral pulp processed in flotatio
n circuits. Imperatives for a more detailed focus on circuit water quality
and its control have come from increasing requirements to use relatively im
pure primary water supplies (e.g. high salinity, treated sewage) and high p
roportions of recycle from tailings dams, thickener overflows, dewatered an
d filter products. An integrated methodology for examining process water qu
ality and its effect on minerals separation has been developed coupled with
minerals surface chemistry across the complete processing circuit. Unrecog
nised factors, including varying proportions of water streams (daily or hou
rly), colloidal precipitation, highly variable pH and Eh, reaction and diss
olution of minerals, minerals surface layer coatings, residual reagents and
their reaction products, and microbiological activity have been studied in
eight mineral processing circuits. The methodology combines: solution surv
ey and modelling; microbiological surveys; minerals surface analysis and mo
delling; and process response. It has been possible to match the predicted
(model) pulp chemistry with that measured from surveys of the solution and
mineral surfaces. Treatment methods have included: monitored and balanced s
tream combinations; organic species removal; flocculation and aggregation;
induced precipitation; dissolved air flotation; ageing (oxidation, UV expos
ure); and chemical surface conditioning of minerals. Some specific achievem
ents from the methodology applied in plant and laboratory testing, with exa
mples from case studies, will be described.