The capabilities of one-dimensional photonic band-gap (PBG) structures to s
imultaneously phase-match several optical fields with different frequencies
propagating in a dispersive medium are examined. A dispersion relation for
an infinite one-dimensional PBG structure whose unit cell consists of thre
e different materials is derived. Analysis of this dispersion relation show
s that structures of this type provide additional degrees of freedom in dis
persion control relative to conventional, binary one-dimensional PBG struct
ures. In particular, the increase in the number of layers with different re
fractive indices in a unit cell of a PBG structure allows a larger number o
f optical fields with different frequencies to be simultaneously phase-matc
hed. The possibilities of using this property of ternary PBG structures for
synthesizing trains of subfemtosecond pulses are discussed.