W. In-hwang et al., Effect of external electromagnetic field and bias voltage on the chemical vapor growth of the carbon micro-coils and their properties, MAT SCI E B, 86(1), 2001, pp. 1-6
Carbon micro-coils were obtained by the chemical vapor deposition using a N
i-catalytic pyrolysis of acetylene at 770 degreesC with hydrogen sulfide as
impurity, with and without an external electromagnetic field (EM) and appl
ying a DC and/or AC bias voltage to the substrate. The effects of the EM fi
eld and bias voltage on the growth rate, morphology and properties of the a
s-grown carbon micro-coils were examined. A pale red-purple light emission
was observed during the reaction. The EM field resulted in full decompositi
on of acetylene and coil yield of 1.6-2.3 times higher than that without th
e external EM field was obtained. The coil yield obtained by the applicatio
n of bias voltage increased linearly with the increasing of bias voltage. T
he coil yield obtained with 400 V DC bias and 1000 V AC bias with the exter
nal EM field were 2.2 and 2.3 times higher than that without the EM field a
nd no applied bias, respectively. The very regular-coiled carbon fibers wit
h a flat fiber cross-section and irregular-coiled carbon fibers with a circ
ular fiber cross-section were obtained with the EM field and without the EM
field irrespective of the bias voltage, respectively, (C) 2001 Elsevier Sc
ience B.V. All rights reserved.