Co-ordination chemistry of a novel diphosphine ligand containing a P-N-Si-N-P backbone

Citation
Ml. Clarke et al., Co-ordination chemistry of a novel diphosphine ligand containing a P-N-Si-N-P backbone, PHOSPHOR SU, 168, 2001, pp. 329-332
Citations number
14
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
ISSN journal
10426507 → ACNP
Volume
168
Year of publication
2001
Pages
329 - 332
Database
ISI
SICI code
1042-6507(2001)168:<329:CCOAND>2.0.ZU;2-O
Abstract
A novel multifunctionalised diphosphine ligand containing a P-N-Si-N-P back bone ha, been prepared and studied. The ligand, Ph2PN(Py)Si(Me)(2)N(Py)PPh2 from complexes with platinum and palladium containing six membered M-P-N-S i-N-P heterocycles. The structure, synthesis, and reactivity of these heter ocycles is discussed.