Synthesis of tin-containing heterocyclic compounds by the reaction of 1,3,5,2,4,6-trichalcogenatristannin with 1,3-dipoles

Authors
Saito, M Nakano, S Yoshioka, M
Citation
M. Saito et al., Synthesis of tin-containing heterocyclic compounds by the reaction of 1,3,5,2,4,6-trichalcogenatristannin with 1,3-dipoles, PHOSPHOR SU, 168, 2001, pp. 429-432
Citations number
7
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
ISSN journal
10426507 → ACNP
Volume
168
Year of publication
2001
Pages
429 - 432
Database
ISI
SICI code
1042-6507(2001)168:<429:SOTHCB>2.0.ZU;2-#
Abstract
Reaction of 1,3,5,2,4,6-trithiatristannin with 2,4,6-tri-t-butylbenzonitril e oxide gave the 1,3,5,2-oxathiazastannole quantitatively. Reaction of 1,3, 2,4-dithiadistannetane with 2,4,6-tri-t-butylbenzonitrile oxide also quanti tatively but slowly afforded the 1,3,5,2-oxathiazastannole. Reaction of 1,3 ,5;1,4,6-triselenatristannin with 2,4,6-tri-t-butylbenzonitrile oxide gave 1,3,5,2-oxaselenazastannole. The thermal behavior of the oxaselenazastannol e was unusual.