H. Letholsen et al., FORMATION OF NANOCRYSTALLINE SURFACE-LAYERS BY ANNEALING AND THEIR ROLE IN FILIFORM CORROSION OF ALUMINUM SHEET, Journal of the Electrochemical Society, 144(7), 1997, pp. 196-197
Annealing of specific rolled aluminum alloys at temperatures above 300
degrees C causes a significant increase in the filiform corrosion sus
ceptibility of the painted substrate. As demonstrated for a selected s
ubstrate (AA8006), the increased susceptibility is related to the form
ation of a thin, (electro-)chemically active nanocrystalline layer at
the surface as a result of the annealing treatment. The corrosion resi
stance is significantly improved by removing the layer by etching duri
ng surface treatment. Possible causes of layer formation and its activ
ity are discussed.