The pathway of the reaction between [(Me3Si)(2)N](2)S and SeCl4

Authors
Maaninen, A Ahlgren, M Ingman, P Laitinen, RS
Citation
A. Maaninen et al., The pathway of the reaction between [(Me3Si)(2)N](2)S and SeCl4, PHOSPHOR SU, 168, 2001, pp. 485-488
Citations number
4
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
ISSN journal
10426507 → ACNP
Volume
168
Year of publication
2001
Pages
485 - 488
Database
ISI
SICI code
1042-6507(2001)168:<485:TPOTRB>2.0.ZU;2-9
Abstract
The reaction of [(Me3Si)(2)N](2)S with an equimolar amount of SeCl4 in CS2 or CH2Cl2 at -70 degreesC provides a route to 1,5-Se2S2N4 in a good yield. When the reaction is carried out in dioxane at +50 degreesC five membered h eterocycle (SSe2N2Cl)(2) is formed. The product is identified and character ized using X-Ray diffraction, Raman spectroscopy, mass spectroscopy and NMR spectroscopy. Se-77 MAS NMR study of the 1,5-Se2S2N4 is reported.