Reactions of organosiloxanes and silicon monoxide

Authors
Aspinall, GM Russell, CA Timms, PL
Citation
Gm. Aspinall et al., Reactions of organosiloxanes and silicon monoxide, PHOSPHOR SU, 168, 2001, pp. 535-538
Citations number
8
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
ISSN journal
10426507 → ACNP
Volume
168
Year of publication
2001
Pages
535 - 538
Database
ISI
SICI code
1042-6507(2001)168:<535:ROOASM>2.0.ZU;2-E
Abstract
Lithium salts of primary amines react readily with organosiloxanes, cleavin g the Si-O bonds to produce amidosiloxanes of the form [(RN(H)]Si(Me)(2)O]( -) as lithium salts. These amidosiloxanes aggregate forming large cage comp lexes, several of which are described herein.