Synthesis and characterization of stable (triphenylmethyl)silanetriol

Authors
Yoo, BR Kim, JH Lee, ME Jung, IN
Citation
Br. Yoo et al., Synthesis and characterization of stable (triphenylmethyl)silanetriol, PHOSPHOR SU, 168, 2001, pp. 551-554
Citations number
11
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
ISSN journal
10426507 → ACNP
Volume
168
Year of publication
2001
Pages
551 - 554
Database
ISI
SICI code
1042-6507(2001)168:<551:SACOS(>2.0.ZU;2-I
Abstract
The (triphenylmethyl)silanetriol (1) was obtained in good yield by the hydr olysis of (triphenylmethyl)trichlorosilane, prepared by the Friedel-Crafts alkylation of benzene with (trichloromethyl)trichlorosilane in the presence of aluminum chloride, with ice. The single crystal of [1(.)THF] for X-ray diffraction was grown as colorless in a saturated THF solution. The solid s tructure of [1(.)THF] was disclosed to be two-dimensional array in head to head hydrogen-bonding fashion.