Synthesis and characterisation of N-alkyl-2-mercaptoacetamide complexes ofgallium (III)

Citation
A. Kaushik et al., Synthesis and characterisation of N-alkyl-2-mercaptoacetamide complexes ofgallium (III), PHOSPHOR SU, 168, 2001, pp. 591-594
Citations number
11
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
ISSN journal
10426507 → ACNP
Volume
168
Year of publication
2001
Pages
591 - 594
Database
ISI
SICI code
1042-6507(2001)168:<591:SACONC>2.0.ZU;2-9
Abstract
N-alkyl-2-mercaptoacetamides of gallium having general formula [RNHC(O)CH2S ](3)Ga, where R = C2H5, n-C3H7, i-C3H7, n-C4H9, i-C4H9, sec-C4H9 have been prepared and characterised by elemental analysis and spectral (IR, H-1 & C- 13 NMR) studies. The complexes appear to exist in two conformational isomer ic forms in solution and the probable structure for both the isomers have b een proposed.