Significant multiple electron capture has been found in collisions of 46 Me
V/u Pb81+ ions with thin carbon foils. An increase in the many-electron cap
ture probability has been observed for the thinnest targets, which is contr
ary to the normally assumed process of subsequent single-electron capture i
n the bulk. This shows the significant contribution of the surface for mult
iple electron capture, Further evidence is found for a strongly reduced cap
ture probability from the exit surface as compared to the entrance surface.
Absolute yields for electron capture and projectile ionization are present
ed and discussed within a Monte-Carlo simulation.