B. Ptaszynski et A. Zwolinska, Synthesis and properties of solid complexes of lanthanum, cerium, neodymium and erbium with N-phosphonomethylglycine, POL J ENV S, 10(4), 2001, pp. 257-262
Water-soluble complexes of lanthanum(III), cerium(III), neodymium(III) and
erbium(III) with N-Phosphonomethylglycine (glyphosate, NPMG) of the general
formulae: LaC3H5NO5P .H2O, CeC3H5NO5P .H2O, NdC3H5NO5P .1,5H(2)O, ErC3H5NO
5P . 2H(2)O were synthesized. Their solubility in water was determined. The
rmal, diffractometric and IR spectrophotometric analyses were carried out.
It was found that the lanthanide ions are bonded to N-phosphonomethylglycin
e through the oxygen atoms of the carboxylic and phosphonate groups and the
nitrogen atom of the amine group. The final products of thermal decomposit
ion at 900 degreesC were determined.