Electrochemical synthesis, X-ray diffraction and spectroscopic characterisation of Co(II) compounds with [(4-methylphenyl)sulfonyl]-1H-imino-2-phenyl-2-oxazolines

Authors
Castro, J Cabaleiro, S Perez-Lourido, P Romero, J Garcia-Vazquez, JA Sousa, A
Citation
J. Castro et al., Electrochemical synthesis, X-ray diffraction and spectroscopic characterisation of Co(II) compounds with [(4-methylphenyl)sulfonyl]-1H-imino-2-phenyl-2-oxazolines, POLYHEDRON, 20(18), 2001, pp. 2329-2337
Citations number
17
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
POLYHEDRON
ISSN journal
02775387 → ACNP
Volume
20
Issue
18
Year of publication
2001
Pages
2329 - 2337
Database
ISI
SICI code
0277-5387(20010815)20:18<2329:ESXDAS>2.0.ZU;2-N
Abstract
The electrochemical oxidation of anodic cobalt in acetonitrile solutions of [(4-methylphenyl)sulfonyl]-1H-imino-2-phenyl-2-oxazoline ligands, [HTs-ROz ], affords compounds of general formula [Co(Ts-ROz)(2)]. All complexes have been characterised by microanalysis, IR and UV-Vis spectroscopy, magnetic measurements and, in the cases of HTs-4(i)PrOz, [Co(Ts-Oz)(2)], [Co(Ts-4MeO z)(2)], [Co(Ts-4(i)PrOz)(2)] and [Co(Ts-4EtOz)(2)], by single-crystal X-ray diffraction. (C) 2001 Elsevier Science Ltd. All rights reserved.