The hydrogenation of C-5 alkynes over palladium catalysts

Authors
Jackson, SD Hamilton, CA Kelly, GJ de Bruin, D
Citation
Sd. Jackson et al., The hydrogenation of C-5 alkynes over palladium catalysts, REACT KIN C, 73(1), 2001, pp. 77-82
Citations number
12
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
REACTION KINETICS AND CATALYSIS LETTERS
ISSN journal
01331736 → ACNP
Volume
73
Issue
1
Year of publication
2001
Pages
77 - 82
Database
ISI
SICI code
0133-1736(2001)73:1<77:THOCAO>2.0.ZU;2-R
Abstract
The hydrogenation of 1-pentyne and 2-pentyne was studied over palladium cat alysts. The internal triple bond hydrogenated faster than the terminal and a particle size effect was observed on the rate of hydrogenation and isomer isation.